Stereoselective Synthesis of Phosphoryl Derivatives

被引：1

作者：

Durst, H. D. ^{[2
]}

Rohrbaugh, D. K. ^{[2
]}

Munavalli, S. ^{[1
]}

机构：

[1] SAIC, Gunpowder Branch, Aberdeen Proving Ground, MD 21010 USA

[2] USA, Edgewood Chem Biol Ctr, Aberdeen Proving Ground, MD USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 11期

关键词：

Alkylphosphinates; dialkylphosphites; mass spectral characterization; Michaelis-Arbuzov reaction; stereoselectivity; H-DIMETHYLPHOSPHONATE; RING PHOSPHITES; ESTERS; STEREOCHEMISTRY; CHEMISTRY; SALTS;

D O I：

10.1080/10426500802591655

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dialkylphosphonites with N-(bromomethyl) phthalimide furnishes alkyl phenyl hydrogenphosphinates, dialkyl phenylphosphonates, and N[(bromomethyl)phthalimido)]-phosphinates. The stereoselectivity of the primary product of the reaction appears to increase with the increasing size of the groups attached to the phosphorus atom.

引用

页码：2902 / 2909

页数：8

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