Redox Activity of Sodium Vanadium Oxides towards Oxidation in Na Ion Batteries

被引：9
|
作者：
Adamczyk, Evan [1 ]
Gnanavel, Muthaiyan [1 ]
Pralong, Valerie [1 ]
机构：
[1] Normandie Univ, ENSICAEN, UNICAEN, CNRS,CRISMAT, F-14000 Caen, France
来源：
MATERIALS | 2018年 / 11卷 / 06期
关键词：
Na2V3O7; sodium vanadate; Na-ion batteries; Na4V2O7; HIGH-PERFORMANCE CATHODE; CRYSTAL-STRUCTURE; ENERGY-STORAGE; NA2V3O7; ELECTRODES; V2O5;
D O I：
10.3390/ma11061021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The search for new materials that could be used as electrode material for Na-ion batteries is one of the most challenging issues of today. Many transition metal oxide families as well as transition metal polyanionic frameworks have been proposed over the last five years. In this work, we report the sodium extraction from Na2V3O7, which is a tunnel type structure built of [V3O7](2-) nanotubes held by sodium ions. We report a reversible charge capacity of 80 mAh/g at 2.8 V vs. Na+/Na due to the V5+/V4+ redox activity. No oxygen redox activity has been observed for this material nor for the vanadium (5+) oxide Na4V2O7.
引用
收藏
页数：8
相关论文
共 50 条
  • [1] Advanced Vanadium Oxides for Sodium-Ion Batteries
    Zhang, Xianghua
    Zhang, Zongbin
    Xu, Shitan
    Xu, Chen
    Rui, Xianhong
    ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (49)
  • [2] Synergistic effect of different configurations on the anionic redox reaction in Na-deficient oxides for sodium ion batteries
    Liu, Qiong
    Zheng, Wei
    Su, Xin
    Zhang, Xuan
    Han, Ning
    Wang, Zhenyu
    Luo, Jiangshui
    Lu, Zhouguang
    Fransaer, Jan
    CHEMICAL ENGINEERING JOURNAL, 2023, 452
  • [3] Stabilizing Reversible Oxygen Redox Chemistry in Layered Oxides for Sodium-Ion Batteries
    Cao, Xin
    Li, Haifeng
    Qiao, Yu
    Li, Xiang
    Jia, Min
    Cabana, Jordi
    Zhou, Haoshen
    ADVANCED ENERGY MATERIALS, 2020, 10 (15)
  • [4] Effect of ion stabilization and thermal annealing on cycling behavior of bilayered vanadium oxides in Na-ion batteries
    Clites, Mallory
    Pomerantseva, Ekaterina
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [5] A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries
    Han, Man Huon
    Gonzalo, Elena
    Singh, Gurpreet
    Rojo, Teofilo
    ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (01) : 81 - 102
  • [6] Towards stable Na-rich layered transition metal oxides for high energy density sodium-ion batteries
    Do, Joongyeop
    Kim, Inkyung
    Kim, Heejin
    Jung, Yousung
    ENERGY STORAGE MATERIALS, 2020, 25 : 62 - 69
  • [7] Ion exchange membranes for vanadium redox flow batteries
    Wu, Xiongwei
    Hu, Junping
    Liu, Jun
    Zhou, Qingming
    Zhou, Wenxin
    Li, Huiyong
    Wu, Yuping
    PURE AND APPLIED CHEMISTRY, 2014, 86 (05) : 633 - 649
  • [8] Strategy towards high ion selectivity membranes for all-vanadium redox flow batteries
    Zhao, Nana
    Platt, Alison
    Riley, Harry
    Qiao, Ruoxi
    Neagu, Roberto
    Shi, Zhiqing
    JOURNAL OF ENERGY STORAGE, 2023, 72
  • [9] Structural evolution of Na-rich spinel oxides involving anionic redox reaction for Na-ion batteries
    Su, Bizhe
    Liang, Hanqin
    Zhao, Xiaohui
    Zhang, Tao
    Zhou, Yu
    Yu, Denis Y. W.
    ELECTROCHIMICA ACTA, 2023, 440
  • [10] Ion Effects on Vanadium Transport in Nafion Membranes for Vanadium Redox Flow Batteries
    Lawton, Jamie S.
    Jones, Amanda M.
    Tang, Zhijiang
    Lindsey, Melanie
    Zawodzinski, Thomas
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (13) : A2987 - A2991
12345