Effective bulk composition changes due to cooling: a model predicting complexities in retrograde reaction textures

Diffusive processes are a strong function of temperature. Thus, during cooling of rocks, mineral grains may develop zoning profiles as successively larger parts of the grain ''close'' to the diffusive exchange with the rock. One of the consequences of this process is that, during cooling, successively larger parts of zoned minerals (depending on grain size) are effectively removed from the reacting part of the rock volume. Thus, the effective bulk composition of metamorphic rocks changes during cooling and the rate of its change will be a function of grain size. Because the sequence of metamorphic reactions seen by a given rock is a strong function of its bulk composition, this process may have the consequence that two rocks of identical overall bulk composition, but of different grain size, may experience a different sequence of reactions. Qualitatively identical peak paragenesis may therefore react to form qualitatively different retrograde reaction textures. The model is applied to examples in the pelitic system. There, garnet is usually the slowest diffusing phase developing zoning profiles during cooling and the effective removal of garnet from the reacting rock volume will cause changes of the effective bulk composition. It is shown that, during cooling of pelitic rocks from amphibolite facies conditions, typical aluminous peak parageneses of garnet-muscovite-kyanite +/- biotite may react to form either staurolite, chlorite or muscovite (or different combinations thereof), depending on grain size. During cooling from the granulite facies, aluminous peak parageneses of garnet-cordierite-sillimanite may form biotite, either on the expense of cordierite or garnet, also depending on grain size. The two examples are illustrated with a series of reaction textures reported for amphibolite and granulite terrains in the literature.