Effect of high pressure on the kinetics and mechanism of thermolysis of organic peroxides in solution

被引：1

作者：

Antonovskii, VL ^{[1
]}

Zhulin, VM

机构：

[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia

[2] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow 119992, Russia

来源：

KINETICS AND CATALYSIS | 2003年 / 44卷 / 01期

关键词：

D O I：

10.1023/A:1022520717880

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review analyzes published data and experimental results obtained by the authors concerning the effect of high pressure on the chemical kinetics of thermal decomposition of the main types of organic and organosilicon peroxides in solution. The volume effect of activation was found to depend on the mechanism of peroxide decomposition and on the properties of solvents.

引用

页码：74 / 81

页数：8

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