Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAlO4+xF1-x solid solution phosphor

被引:0
|
作者
Wang Yan-Ze [1 ]
Ma Jian [1 ]
Sun Liang [1 ]
Li Rui [1 ]
Wang Da-Jian [1 ]
机构
[1] Tianjin Univ Technol, Sch Mat Sci & Engn, Inst Mat Phys, Tianjin 300384, Peoples R China
基金
中国国家自然科学基金;
关键词
energy transfer; solid solution; red emission; phosphor; YELLOW PHOSPHORS; WHITE; LUMINESCENCE; SUBSTITUTION; CONVERSION;
D O I
10.1088/1674-1056/23/10/107805
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The photoluminescence properties and energy transfer of a new Ce3+/Pr3+/Eu3+ co-doped solid-solution composition of Sr2.975-xLaxAlO4+xF1-x (LSAF) phosphor are investigated. Upon doping Pr3+ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition of D-1(2) -> H-3(4). Addition of Eu3+ to LSAF:Ce3+, Pr3+ phosphor results in a sharp emission peaked at 675 nm for the D-5(0) -> F-7(3) transition and an increase of the intensity of red emission for Pr3+ with increasing Eu3+ concentration. The pathways of energy transfer among Ce3+, Pr3+, and Eu3+ are proposed to be responsible for color addition of a red component to the primary yellow emission, enabling a potential adjustable color for blue excitable warm white.
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页数:5
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