Catalytic performances of Ni-CaO-mayenite in CO2 sorption enhanced steam methane reforming

被引：65
|
作者：
Cesario, Moises R. [1 ,2 ]
Barros, Braulio S. [3 ]
Courson, Claire [1 ]
Melo, Dulce M. A. [2 ]
Kiennemann, Alain [1 ]
机构：
[1] Univ Strasbourg, CNRS, UMR 7515, Inst Chim & Proc Energie Environm & Sante, F-67087 Strasbourg, France
[2] Univ Fed Rio Grande do Norte, Dept Chem, BR-59072970 Natal, RN, Brazil
[3] Univ Fed Rio Grande do Norte, Sch Sci & Technol, BR-59078970 Natal, RN, Brazil
来源：
FUEL PROCESSING TECHNOLOGY | 2015年 / 131卷
关键词：
Steam methane reforming; CO2; sorption; Microwave assisted self-combustion method; Hydrogen; CARBON-DIOXIDE; CALCIUM-OXIDE; HYDROGEN-PRODUCTION; CAPTURE; SORBENTS; TEMPERATURE; CALCINATION; CONVERSION; STABILITY; REMOVAL;
D O I：
10.1016/j.fuproc.2014.11.028
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
N-CaO-mayenite (Ca12Al14O33) catalysts for the CO2 Sorption Enhanced Steam Methane Reforming (SE-SMR) have been developed using the microwave assisted self-combustion method of preparation. The sorption of CO2 by CaO shifts the steam reforming and the Water Gas Shift reaction (WGS) towards H-2 production and favors the heat balance of the global reaction. The CO2 sorption has been studied on materials with different CaO/Ca12Al14O33 ratios and for different types of preparation. The specific surface area of materials, the temperature of Ni phases' reducibility and CO2 sorption are all essential for material efficiency. The Ni-CA75MM catalyst was the most active and stable in methane steam reforming with CO2 sorption, even at an unusually low temperature (650 degrees C). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：247 / 253
页数：7
相关论文
共 50 条
  • [1] Effect of Ni precursor salts on Ni-mayenite catalysts for steam methane reforming and on Ni-CaO-mayenite materials for sorption enhanced steam methane reforming
    Di Giuliano, A.
    Gallucci, K.
    Foscolo, P. U.
    Courson, C.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (13) : 6461 - 6480
  • [2] Development of a Ni-CaO-mayenite combined sorbent-catalyst material for multicycle sorption enhanced steam methane reforming
    Di Giuliano, A.
    Giancaterino, F.
    Courson, C.
    Foscolo, P. U.
    Gallucci, K.
    [J]. FUEL, 2018, 234 : 687 - 699
  • [3] Sorption enhanced steam methane reforming by Ni-CaO materials supported on mayenite
    Di Giuliano, A.
    Girt, J.
    Massacesi, R.
    Gallucci, K.
    Courson, C.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (19) : 13661 - 13680
  • [4] Green hydrogen production from sorption-enhanced steam reforming of biogas over a Pd/Ni-CaO-mayenite multifunctional catalyst
    Dang, Chengxiong
    Xia, Huanhuan
    Yuan, Shuting
    Wei, Xingchuan
    Cai, Weiquan
    [J]. RENEWABLE ENERGY, 2022, 201 : 314 - 322
  • [5] Hydrotalcite as CO2 sorbent for sorption-enhanced steam reforming of methane
    Reijers, HTJ
    Valster-Schiermeier, SEA
    Cobden, PD
    van den Brink, RW
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (08) : 2522 - 2530
  • [6] Catalytic steam methane reforming enhanced by CO2 capture on CaO based bi-functional compounds
    Micheli, Francesca
    Sciarra, Manuela
    Courson, Claire
    Gallucci, Katia
    [J]. JOURNAL OF ENERGY CHEMISTRY, 2017, 26 (05) : 1014 - 1025
  • [7] Catalytic steam methane reforming enhanced by CO2 capture on CaO based bi-functional compounds
    Francesca Micheli
    Manuela Sciarra
    Claire Courson
    Katia Gallucci
    [J]. Journal of Energy Chemistry, 2017, (05) : 1014 - 1025
  • [8] Ni catalysts for sorption enhanced steam methane reforming
    Ochoa-Fernandez, Esther
    Lacalle-Vila, Claudia
    Christensen, Kjersti O.
    Walmsley, John C.
    Ronning, Magnus
    Holmen, Anders
    De Chen
    [J]. TOPICS IN CATALYSIS, 2007, 45 (1-4) : 3 - 8
  • [9] Ni catalysts for sorption enhanced steam methane reforming
    Esther Ochoa-Fernández
    Claudia Lacalle-Vilà
    Kjersti O. Christensen
    John C. Walmsley
    Magnus Rønning
    Anders Holmen
    De Chen
    [J]. Topics in Catalysis, 2007, 45 : 3 - 8
  • [10] Sorption enhanced steam methane reforming byNi/CaO/mayenite combined systems: Overview of experimental results fromEuropean research projectASCENT
    Di Giuliano, Andrea
    Gallucci, Katia
    Di Carlo, Andrea
    Stendardo, Stefano
    Courson, Claire
    Foscolo, Pier Ugo
    [J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2020, 98 (09): : 1907 - 1923
12345