Cyclopentadienyliron dicarbonyl dimer: A simple tool for the hydrosilylation of aldehydes and ketones under air

被引：15
|
作者：
Jung, Thais Cordeiro [1 ]
Argouarch, Gilles [1 ]
van de Weghe, Pierre [1 ]
机构：
[1] Univ Rennes 1, UMR CNRS 6226, Inst Sci Chim Rennes, UFR Sci Biol & Pharmaceut,Equipe PNSCM, 2 Ave Prof Leon Bernard, F-35043 Rennes, France
来源：
CATALYSIS COMMUNICATIONS | 2016年 / 78卷
关键词：
Aldehydes; Hydrosilylation; Iron; Ketones; Reduction; IRON-CATALYZED HYDROSILYLATION; CARBONYL-COMPOUNDS; ENANTIOSELECTIVE HYDROSILYLATION; ASYMMETRIC HYDROSILYLATION; COMPLEXES; REDUCTION; EFFICIENT; LIGANDS; METAL; TEMPERATURE;
D O I：
10.1016/j.catcom.2016.01.033
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The readily available iron complex [CpFe(CO)(2)](2) (1) exhibits good catalytic activity in the hydrosilylation of aldehydes and ketones in the presence of diethoxymethylsilane. The procedure described is air-tolerant and applicable to a wide range of substrates. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：52 / 54
页数：3
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