Preparation of enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine and their behaviour as chiral solvating agents: study of diastereochemic association by Job's plots and intermolecular NOE measurements

被引：29

作者：

Port, A

Virgili, A ^{[1
]}

Alvarez-Larena, A

Piniella, JF

机构：

[1] Univ Autonoma Barcelona, Dept Quim, Unitat Quim Organ, E-08193 Barcelona, Spain

[2] Univ Autonoma Barcelona, Dept Geol, E-08193 Barcelona, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 18期

关键词：

D O I：

10.1016/S0957-4166(00)00334-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomers of 1-(1-naphthyl)-2,2-dimethylpropylamine have been obtained and considered as chiral solvating agents against several compounds. The formed complexes have been studied with the aid of the nuclear Overhauser effect and its stoichiometry by the method of continuous variations. Two diastereoisomeric complexes present similar geometry of association by pi-pi -stacking of the aromatic rings and by hydrogen bonding of the functional groups. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3747 / 3757

页数：11

共 4 条

[1] Preparation and behavior of (R)- and (S)-2,2,2-trifluoro-1-(1-pyrenyl)ethanol as chiral solvating agents:: study of the diastereomeric association by Job's plots, intermolecular NOE and binding constants
Muñoz, A
Virgili, A
TETRAHEDRON-ASYMMETRY, 2002, 13 (14) : 1529 - 1534
[2] Preparation of enantiomers of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene. Conformational study and their behaviour as chiral solvating agents
Port, A
Virgili, A
Jaime, C
TETRAHEDRON-ASYMMETRY, 1996, 7 (05) : 1295 - 1302
[3] Preparation of (R)- and (S)-1-adamantyl-9-anthrylmethanol.: Conformational study and their behaviour as chiral solvating agents
Almer, S
Cervelló, E
Jaime, C
Virgili, A
TETRAHEDRON-ASYMMETRY, 1999, 10 (19) : 3719 - 3725
[4] Preparation of Two New Diasteromeric Chiral Stationary Phases Based on (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic Acid and (R)- or (S)-1-(1-Naphthyl) ethylamine and Chiral Tethering Group Effect on the Chiral Recognition
Agneeswari, Rajalingam
Sung, Ji Yeong
Jo, Eun Sol
Jeon, Hee Young
Tamilavan, Vellaiappillai
Hyun, Myung Ho
MOLECULES, 2016, 21 (08)

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