Access to α,β-unsaturated carboxylic acids through water-soluble palladium catalyzed hydroxycarbonylation of alkynes using water as the solvent

被引：9

作者：

Lv, Jinhe ^{[1
]}

Zong, Lingbo ^{[1
]}

Zhang, Jinrong ^{[1
]}

Song, Jiaxin ^{[1
]}

Zhao, Jinyu ^{[1
]}

Zhang, Kai ^{[1
]}

Zhou, Ziqin ^{[1
]}

Gao, Mingjie ^{[2
]}

Xie, Congxia ^{[1
]}

Jia, Xiaofei ^{[1
]}

Ren, Xinyi ^{[3
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Shandong Key Lab Biochem Anal, Qingdao 266042, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

[3] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200241, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2021年 / 11卷 / 14期

基金：

中国国家自然科学基金;

关键词：

CHEMICAL-REACTIONS; TERMINAL ALKYNES; CARBON-DIOXIDE; CO-CATALYSIS; PD-CATALYST; HYDROCARBOXYLATION; CARBONYLATION; OLEFINS; LIGAND; ALDEHYDES;

D O I：

10.1039/d1cy00699a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A sulfoxantphos modified palladium-catalyzed synthesis of alpha,beta-unsaturated carboxylic acids from alkynes with CO and H2O was described. The atom-economic hydroxycarbonylation of various symmetrical and unsymmetrical alkynes can be achieved with chemo-, stereo-, and regioselectivity, affording the corresponding carboxylic acids in good to excellent yields. Using water as the reaction solvent, the water-soluble palladium catalyst was easily separated from the product and could be reused for 5 cycles.

引用

页码：4708 / 4713

页数：6

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