Studies of Substituents Impact on the Photophysical Properties of 8-Hydroxyquinoline Derivatives

被引:3
|
作者
Gao, Li-Bin [1 ]
Kang, Wu-Kui [1 ]
Yan, Shi-Hai [1 ]
Yang, Chun-Peng [2 ]
机构
[1] Qingdao Agr Univ, Inst Chem & Pharm, Qingdao 266109, Peoples R China
[2] Chinese Acad Sci, Qingdao Inst Biomass Energy & Bioproc Technol, Qingdao 266101, Peoples R China
关键词
OPTICAL-PROPERTIES; COUPLING REACTION; COMPLEXES; COPPER; LIGANDS; ARYL; ELECTROLUMINESCENCE; FLUORESCENT; ZINC;
D O I
10.1002/hc.21301
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Five new 8-hydroxyquinoline derivatives L1-L5 were synthesized and characterized by different techniques, such as Nuclear Magnetic Resonance (NMR), electrospray ionization mass spectra, elemental analysis, ultraviolet-visible, and photoluminescence spectra. The structure of (E)-2-{2-[5-(phenylethynyl)thiophen-2-yl] ethenyl}quinolin-8-ol (L3) was confirmed by X-ray crystallography. In this structure, intermolecular hydrogen bonds were found between OH hydrogen donors of one monomer and the oxygen atom of the next one. Photophysical studies show that different substitutes affect the absorption wavelength and emission color. (C) 2015 Wiley Periodicals, Inc.
引用
收藏
页码:54 / 62
页数:9
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