Thermal lens micro optical systems

被引:37
|
作者
Tokeshi, M
Yamaguchi, J
Hattori, A
Kitamori, T
机构
[1] KAST, Integrated Chem Project, Kawasaki, Kanagawa 2130012, Japan
[2] Nippon Sheet Glass Corp Ltd, Micro Chem Chip Project, Informat Technol Co, Sagamihara, Kanagawa 2291189, Japan
[3] Univ Tokyo, Dept Appl Chem, Grad Sch Engn, Tokyo 1138656, Japan
关键词
D O I
10.1021/ac049011r
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper describes two types of miniaturized thermal lens optical systems that use optical fibers, SELFOC microlenses and light sources. The first system consists of a compact diode pumped solid-state laser (532 nm) as an excitation light source, a laser diode (635 nm) as a probe light source, an acoustoptic modulator as an excitation light modulator, fiber-based and conventional optics, and a detection system that combines a pinhole, an interference filter, and a photodiode. The second system consists of two laser diodes as the excitation (658 nm) and probe (780 nm) light sources, fiber-based optics, and the same detection system as the first one. The performance of the two systems was evaluated by the limit of detection (LOD) using standard solutions of sunset yellow (SY) and nickel(II) phthalocyaninetetrasulfonic acid tetrasodium salt (NiP). The LODs of the first system for SY and second system for NiP were calculated to be 3.7 x 10(-8) (1.7 x 10(-6) AU) and 7.7 x 10(-9) M (3.4 x 10(-6) AU), respectively. These results were consistent with the expected values obtained from photothermal parameters.
引用
收藏
页码:626 / 630
页数:5
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