Enantioselective synthesis of planar-chiral metacyclophanes through rhodium-catalyzed alkyne cyclotrimerization

被引：76
|
作者：
Tanaka, Ken [1 ]
Sagae, Hiromi
Toyoda, Kazuki
Noguchi, Keiichi
Hirano, Masao
机构：
[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Grad Sch Engn, Koganei, Tokyo 1848588, Japan
[2] Tokyo Univ Agr & Technol, Instrumentat Anal Ctr, Koganei, Tokyo 1848588, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 06期
关键词：
D O I：
10.1021/ja0679127
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have achieved the first catalytic enantioselective synthesis of planar-chiral metacyclophanes by means of cationic rhodium(I)/(R)-H-8-BINAP complex-catalyzed alkyne cyclotrimerization. This reaction represents a versatile new method for the preparation of planar-chiral [7]-[10] metacyclophanes.
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收藏
页码：1522 / +
页数：3
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