Copper Triflate Catalyzed Oxidative α-Allylation of Glycine Derivatives

被引：6
|
作者：
Chen, Ting-Ting [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Coll Chem Engn, 200 Xiaolingwei, Nanjing 210094, Jiangsu, Peoples R China
来源：
SYNLETT | 2017年 / 28卷 / 11期
关键词：
copper triflate; glycine derivatives; allylation; homoallylic amines; oxygen; TBHP; AMINO CARBONYL-COMPOUNDS; VISIBLE-LIGHT CATALYSIS; CROSS-COUPLING REACTION; H BOND ACTIVATION; TRANSITION-METAL; FUNCTIONALIZATION; ALKYLATION; ADJACENT; NITROGEN; IMINES;
D O I：
10.1055/s-0036-1588158
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper triflate catalyzed oxidative C-H functionalization of glycine derivatives with allyltributyltin has been established using oxygen or tert-butyl hydroperoxide as oxidant. Various glycine esters and glycine amides were suitable substrates for this oxidative allylation reaction and afforded the desired homoallylic amines in moderate to good yields.
引用
收藏
页码：1368 / 1372
页数：5
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