RING-SUBSTITUTION, ENLARGEMENT, AND CONTRACTION BY BASE-INDUCED REARRANGEMENTS OF N-HETEROCYCLIC AMMONIUM SALTS

被引：16

作者：

Tayama, Eiji ^{[1
]}

机构：

[1] Niigata Univ, Fac Sci, Dept Chem, Niigata 9502181, Japan

来源：

HETEROCYCLES | 2016年 / 92卷 / 05期

关键词：

SOMMELET-HAUSER REARRANGEMENT; STEVENS REARRANGEMENT; SIGMATROPIC REARRANGEMENT; CHIRALITY TRANSFER; ALLYLIC AMMONIUM; TRANSITION-STATE; YLIDES; ROUTE; 1-METHYLIDES; AMINES;

D O I：

10.3987/REV-16-837

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An overview of the utility of base-induced Stevens, Sommelet-Hauser, and related sigmatropic rearrangements of N-heterocyclic ammonium salts into various types of N-heterocycles reported after 1970 will be described. The synthetic transformations are classified as N-heterocyclic ring-substitution, ring-enlargement, and ring-contraction.

引用

页码：793 / 828

页数：36

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