Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction

被引：1
|
作者：
Lee, ASY [1 ]
Lin, LS [1 ]
机构：
[1] Tamkang Univ, Dept Chem, Tamsui 251, Taiwan
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 45期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of allyl ketones were synthesized from the mixture of zinc, nitrile and allyl bromide in the presence of AlCl3 via Barbier-type reaction condition. When crotyl bromide was used for the allylation, only the gamma -adduct was produced via the S(E)2' pathway under the reaction condition. (C) 2000 Elsevier Science Ltd. All rights reserved.
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页码：8803 / 8806
页数：4
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