Microwave rapid synthesis of CuxO@polypyrrole nanofibre (PpyNF) composites for supercapacitors

CuxO@polypyrrole nanofibre (PpyNF) composites were synthesized by a simple and fast microwave method. The samples were characterized using X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy; galvanostatic charge-discharge tests, cyclic voltammetry and electrochemical impedance spectroscopy were also conducted. The PpyNF composites showed a maximum specific capacitance of 464.6 F g(-1) at 0.5 A g(-1) with excellent cyclability (95.6% capacitance retention after 2,000 cycles at 1 A g(-1)), thereby demonstrating their excellent potential for application to supercapacitors. An asymmetric supercapacitor based on CuxO@PpyNF//active carbon revealed a maximum gravimetric energy density of 12.50 Wh kg(-1) and power density of 0.38 kW kg (-1).