Kinetics of the oxidation of stainless steel in hot and concentrated nitric acid in the passive and transpassive domains

被引：37
|
作者：
Tcharkhtchi-Gillard, E. [1 ,2 ]
Benoit, M. [1 ]
Clavier, P. [1 ]
Gwinner, B. [1 ]
Miserque, F. [3 ]
Vivier, V. [2 ]
机构：
[1] CEA, Lab Etud Corros Non Aqueuse, DEN, DANS,DPC,SCCME, F-91191 Gif Sur Yvette, France
[2] UPMC, CNRS, UMR 8235, Lab Interfaces & Syst Electrochim, F-75252 Paris 05, France
[3] CEA, Lab Etud Corros Aqueuse, DEN, DANS,DPC,SCCME, F-91191 Gif Sur Yvette, France
来源：
CORROSION SCIENCE | 2016年 / 107卷
关键词：
stainless steel; potentiostatic; xps; acid corrosion; passive film; transpassivity; DIE AUTOKATALYTISCHE NATUR; CORROSION-ELECTROCHEMICAL BEHAVIOR; ZU SALPETRIGER SAURE; RAY PHOTOELECTRON-SPECTROSCOPY; INTERGRANULAR CORROSION; GRAIN-BOUNDARIES; SILICON; MEDIA; PHOSPHORUS; FILMS;
D O I：
10.1016/j.corsci.2016.02.031
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Oxidation of 304L stainless steel was studied in 4 mol/L nitric acid solution at 100 degrees C over a wide potential domain. For different potentials, long-term chronoamperometry experiments coupled with mass loss measurements were performed until steady-state was reached to characterize the corrosion kinetics of the passive and transpassive domains. With EIS and XPS measurements, the passive domain was characterized by the formation of a thin film, the thickness of which was potential dependent. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：182 / 192
页数：11
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