Crystallization kinetics of Zn(Val)SO4 • H2O in mixed solvent of water with acetone

被引：0

作者：

Gao, SL ^{[1
]}

Fang, Y ^{[1
]}

Hu, RZ ^{[1
]}

Chen, SP ^{[1
]}

Shi, QZ ^{[1
]}

机构：

[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 03期

关键词：

Zn(Val)SO4 center dot H2O; mixed solvent; crystallization kinetics; microcalorimetry; enthalpy of solution;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The optimum volume ratio of water. to acetone for Zn(Val)SO4.H2O crystalling from the mixed solvent of water with acetone has been determined, which is 1:10. The,crystal growth process of the compound at 298.15 K is investigated by microcalorimetry. The experimental results show that it obeys the Burton-Cabrera-Frank dislocation theory. Moreover, the enthalpy of solution of Zn(Val)SO4.H2O in water has been measured at 298.15 K. The standard enthalpy of formation of Zn(Val)(2+)(aq) has been calculated.

引用

页码：381 / 385

页数：5

共 14 条

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