Non-covalent intermolecular interactions of colloidal nematic liquid crystals doped with graphene oxide

被引:35
|
作者
Javadian, Soheila [1 ]
Dalir, Nima [1 ]
Kakemam, Jamal [1 ]
机构
[1] Tarbiat Modares Univ, Fac Basic Sci, Dept Phys Chem, POB 14115-175, Tehran, Iran
关键词
Nematic liquid crystal; graphene oxide; phase transition; and intermolecular interactions; INTERACTION PARAMETERS; CORROSION-INHIBITORS; PHASE-TRANSITIONS; CARBON NANOTUBES; MILD-STEEL; DEVICES; THERMODYNAMICS; SPECTROSCOPY; DISPERSIONS; PERFORMANCE;
D O I
10.1080/02678292.2016.1278051
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene oxide (GO) was doped to eutectic uniaxial nematic liquid crystals (NLCs) (E-5CN7) with different percentages to improve the physiochemical properties of NLCs effectively. GO shifts the N-I phase transition temperature to higher values. It has been observed that increasing GO concentration up to 0.75% increases the N-I phase transition temperature substantially while further increase of GO concentration results in an inverse trend. The GO/E-5CN7 non-covalent interactions change the N-I phase transition. The contribution of several terms such as anchoring and polarisation effects on N-I phase transition was quantified as well. The results suggest that the size is an important contributor to GO and liquid crystal interaction. The results show that E-5CN7@GO composites may act as promising candidates to enhance the efficiency of room temperature devices. [GRAPHICS] .
引用
收藏
页码:1341 / 1355
页数:15
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