Study of zinc incorporation on the non-isothermal crystallization in glassy selenium using iso-conversional approach

被引：2
|
作者：
Dohare, C. [1 ]
Mehta, N. [1 ]
机构：
[1] Banaras Hindu Univ, Dept Phys, Glass Sci Lab, Varanasi 221005, Uttar Pradesh, India
来源：
MATERIALS LETTERS | 2015年 / 138卷
关键词：
Crystal growth; Activation energy; Glasses; Metals and alloys; ACTIVATION-ENERGY; KINETIC-ANALYSIS; MODEL-FREE; HEATING RATE; TEMPERATURE; PARAMETERS; RATES; END;
D O I：
10.1016/j.matlet.2014.09.089
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The crystallization kinetics of glassy Se (g-Se) and glassy Se98Zn2 alloy has been studied by means of differential scanning calorimetric (DSC) technique. lso-conversional methods [Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO), Tang and Straink] were used to determine the various kinetic parameters (i.e. crystallization temperature T-alpha, activation energy of crystallization E-alpha) of crystallization process in non-isothermal mode. The monotonous decrement in activation energy, E-alpha with the extent of conversion, a confirms the complex kinetic mechanism of g-Se and Se98Zn2 alloy. The reaction model, 'Avrami-Erofeev' g(alpha)=[- ln(1 - alpha)](1/n) has been followed to describe the crystallization process with n=1.5 for g-Se and n=2.0 for Se98Zn2 alloy. (C) 2014 Elsevier B.V. All rights reserved,
引用
收藏
页码：171 / 174
页数：4
相关论文
共 50 条
  • [1] Iso-conversional kinetic study of non-isothermal crystallization in glassy Se98Ag2 alloy
    C. Dohare
    N. Mehta
    Journal of Thermal Analysis and Calorimetry, 2012, 109 : 247 - 253
  • [2] Iso-conversional kinetic study of non-isothermal crystallization in glassy Se98Ag2 alloy
    Dohare, C.
    Mehta, N.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 109 (01) : 247 - 253
  • [3] Reconciliation of Arrhenius and iso-conversional analysis kinetics parameters of non-isothermal data
    Elder, JP
    THERMOCHIMICA ACTA, 1996, 272 (272) : 41 - 48
  • [4] STUDY OF CRYSTALLIZATION KINETICS IN GLASSY Se100-xBix USING ISO-CONVERSIONAL METHODS
    Srivastava, Sphoorti
    Zulfequar, M.
    Kumar, A.
    JOURNAL OF NON-OXIDE GLASSES, 2010, 2 (02): : 97 - 106
  • [5] Estimation of the Activation Energy for the Non-isothermal Crystallization in Amorphous Se70Te15In15 Alloy Using Iso-conversional Methods
    Patial, Balbir Singh
    Thakur, Nagesh
    Tripathi, S. K.
    SOLID STATE PHYSICS: PROCEEDINGS OF THE 55TH DAE SOLID STATE PHYSICS SYMPOSIUM 2010, PTS A AND B, 2011, 1349 : 539 - +
  • [6] CRYSTALLIZATION KINETICS IN GLASSY Se100-x Inx SYSTEM USING ISO-CONVERSIONAL METHODS
    Shukla, R.
    Agarwal, P.
    Kumar, A.
    CHALCOGENIDE LETTERS, 2010, 7 (04): : 249 - 255
  • [7] Iso-conversional study of crystallization activation energy of amorphous-crystallization transformation for Se79Te20Pb1 glass using non-isothermal differential scanning calorimetry technique
    Vashist, Priyanka
    Patial, Balbir Singh
    Anjali
    Tripathi, S. K.
    Thakur, Nagesh
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2020, 58 (03) : 135 - 140
  • [8] Calorimetric study of crystallization kinetics in ternary alloys of Se-Te-Sn glasses using iso-conversional approach
    Ansari, Rafiullah
    Kumar, Horesh
    BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2020, 59 (06): : 267 - 272
  • [9] Non-Isothermal Kinetics of Phoenix Dactylifera L. Date Palm Seeds Pyrolysis Using Model Fitting and Iso-Conversional Model Free Methods
    El Marouani, Maryam
    El Hamdaoui, Lahcen
    Boulhaoua, Mohammed
    Pienaar, Andrew
    Trif, Laszlo
    Costa, Guy
    Simo-Tagne, Merlin
    Kifani-Sahban, Fatima
    CHEMISTRYSELECT, 2023, 8 (11):
  • [10] NON-ISOTHERMAL CRYSTALLIZATION IN AMORPHOUS SELENIUM FILMS
    GRENET, J
    LARMAGNAC, JP
    MICHON, P
    JOURNAL OF THERMAL ANALYSIS, 1982, 25 (02): : 539 - 562
12345