Synthesis, spectral characterisation and redox studies of copper(I) and silver(I) complexes of N(1)-benzyl-2-(arylazo)imidazoles

被引：0
|
作者：
Das, D [1 ]
Misra, TK [1 ]
Sinha, C [1 ]
机构：
[1] Univ Burdwan Golapbag, Dept Chem, Burdwan 713104, W Bengal, India
来源：
TRANSITION METAL CHEMISTRY | 1998年 / 23卷 / 01期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complexes of general formula [ML2]ClO4 [M = Cu or Ag; L = N(1)-benzyl-2-(arylazo)imidazole] have been prepared and characterised. Spectroscopic data suggest that the complexes are overall tetrahedral with MN4 coordination spheres. Redox studies show a Cu (I/II) couple of ca. 0.5 V versus s.c.e. in MeOH.
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页码：73 / 75
页数：3
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