Reaction of aromatic radical cations with RuCl3•3H2O

被引：5
|
作者：
Michman, M [1 ]
Oron, M
Schaefer, HJ
机构：
[1] Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel
[2] Univ Munster, Inst Organ Chem, Dept Organ Chem, D-48148 Munster, Germany
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2000年 / 65卷 / 06期
关键词：
electrooxidation; electrocatalysis; oxidations; radical cations; ruthenium chloride; benzoquinones; ethers; anilines;
D O I：
10.1135/cccc20000924
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Interactions of RuCl3. 3H(2)O with radical cations of aromatic ethers, 1,4-di-tert-butyl-2,5-dimethoxybenzene, 3,5-di-tert-butyl-1,2-dimethoxybenzene and 2-tert-butyl-1,4-dimethoxybenzene, and with aromatic amines, 2,4,6-tri-tert-butylaniline and N,N,N',N'-tetramethyl-1,4-phenylenediamine, were observed by voltammetry. ESR and UV spectroscopies were used for the study of the the first two ethers. The effect of RuCl3. 3H(2)O was also examined by controlled potential electrolysis.
引用
收藏
页码：924 / 940
页数：17
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