Study on iron-sulfur cluster in gas phase: electronic structure and reactivity

被引：49
|
作者：
Nakajima, A
Hayase, T
Hayakawa, F
Kaya, K
机构：
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 223, Japan
[2] RIKEN, Inst Phys & Chem Res, Wako, Saitama 35101, Japan
来源：
CHEMICAL PHYSICS LETTERS | 1997年 / 280卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(97)01162-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In gas phase, electronic and geometric properties of iron-sulfur cluster (FenSm, n = 1-8, m = 2-6) have been investigated using photoelectron spectroscopy (PES) of their anions and a chemical probe method for their cations. The electron affinities of FenSm greatly change at the composition of n = m, and the reactivity of FenSm+ toward NH3 and C2H2 is enhanced around equally mixed compositions. These results show that the FenSm clusters produced in gas phase seemingly take the structure having alternate bonds between Fe and S atoms, likewise that of an active site of iron-sulfur proteins. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：381 / 389
页数：9
相关论文
共 50 条
  • [1] Synthesis and reactivity of a new octanuclear iron-sulfur nitrosyl cluster
    Kalyvas, Harris
    Coucouvanis, Dimitri
    [J]. INORGANIC CHEMISTRY, 2006, 45 (21) : 8462 - 8464
  • [2] Synthesis, Structure, and Reactivity of Iron-Sulfur Species in Zeolites
    Richard W. Joyner
    Michael Stockenhuber
    Olga P. Tkachenko
    [J]. Catalysis Letters, 2003, 85 : 193 - 197
  • [3] Iron-Sulfur Bond Covalency from Electronic Structure Calculations for Classical Iron-Sulfur Clusters
    Harris, Travis V.
    Szilagyi, Robert K.
    [J]. JOURNAL OF COMPUTATIONAL CHEMISTRY, 2014, 35 (07) : 540 - 552
  • [4] Synthesis, structure, and reactivity of iron-sulfur species in zeolites
    Joyner, RW
    Stockenhuber, M
    Tkachenko, OP
    [J]. CATALYSIS LETTERS, 2003, 85 (3-4) : 193 - 197
  • [5] HIGH-POTENTIAL IRON-SULFUR CLUSTER OF ACONITASE IS A BINUCLEAR IRON-SULFUR CLUSTER
    KURTZ, DM
    HOLM, RH
    RUZICKA, FJ
    BEINERT, H
    COLES, CJ
    SINGER, TP
    [J]. JOURNAL OF BIOLOGICAL CHEMISTRY, 1979, 254 (12) : 4967 - 4969
  • [6] Electronic and Structural Properties of the Double Cubane Iron-Sulfur Cluster
    Elghobashi-Meinhardt, Nadia
    Tombolelli, Daria
    Mroginski, Maria Andrea
    [J]. CATALYSTS, 2021, 11 (02) : 1 - 16
  • [7] Electronic, magnetic structure and water splitting reactivity of the iron-sulfur dimers and their hexacarbonyl complexes: A density functional study
    Uzunova, Ellie L.
    Mikosch, Hans
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2014, 141 (04):
  • [8] Iron-sulfur cluster biosynthesis
    Bandyopadhyay, Sibali
    Chandramouli, Kala
    Johnson, Michael K.
    [J]. BIOCHEMICAL SOCIETY TRANSACTIONS, 2008, 36 : 1112 - 1119
  • [9] STRUCTURE OF IRON-SULFUR CLUSTER IN CHROMATIUM IRON PROTEIN AT 2.25 A RESOLUTION
    CARTER, CW
    ALDEN, RA
    XUONG, NH
    KRAUT, J
    FREER, ST
    [J]. COLD SPRING HARBOR SYMPOSIA ON QUANTITATIVE BIOLOGY, 1971, 36 : 381 - &
  • [10] Iron-sulfur cluster biosynthesis -: Thermatoga maritima IscU is a structured iron-sulfur cluster assembly protein
    Mansy, SS
    Wu, G
    Surerus, KK
    Cowan, JA
    [J]. JOURNAL OF BIOLOGICAL CHEMISTRY, 2002, 277 (24) : 21397 - 21404
12345