Ionic liquids as solvents for polymerization processes-Progress and challenges

被引：329

作者：

Kubisa, Przemyslaw ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

PROGRESS IN POLYMER SCIENCE | 2009年 / 34卷 / 12期

关键词：

Ionic liquids; Polycondensation; Radical polymerization; Ionic polymerization; Solvent properties; FREE-RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; N-ETHYLPYRROLIDINIUM DICYANAMIDE; CHARGE-TRANSFER POLYMERIZATION; DIFFUSION-CONTROLLED REACTIONS; METHYL-METHACRYLATE; MICROWAVE IRRADIATION; CATIONIC-POLYMERIZATION; ANIONIC-POLYMERIZATION; LIVING POLYMERIZATION;

D O I：

10.1016/j.progpolymsci.2009.09.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ionic liquids (ILs) are organic salts that are liquid at ambient temperatures. Ionic liquids have emerged as a new class of solvents for practical applications due to their unique combination of low volatility, chemical stability, high conductivity, wide electrochemical window, ability to dissolve organic and inorganic solutes and gases, and tunable solvent properties. In polymer science ionic liquids are used as solvents for polymerization processes and as components of polymeric materials. In this review the advantages and limitations of application of ionic liquids as solvents for polymerization processes are critically discussed, with special emphasis on results published within last 5 years. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1333 / 1347

页数：15

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