Enhancement of cyclopropanation chemistry in the silver-catalyzed reactions of aryldiazoacetates

被引：135
|
作者：
Thompson, Janelle L. [1 ]
Davies, Huw M. L. [1 ]
机构：
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 19期
关键词：
D O I：
10.1021/ja069314y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
AgSbF6 is an effective catalyst for the reactions of donor/acceptor substituted carbenoids and shows a very different reactivity profile from the traditional rhodium-catalyzed reactions. Most notably, cyclopropanation of sterically hindered alkenes is favorable, and products due to a Wolff rearrangement are not observed. Yields of products obtained are often high (54-96%) with excellent diastereoselectivity (> 94% de).
引用
收藏
页码：6090 / +
页数：3
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