High-frequency MnZn soft magnetic ferrite by engineering grain boundaries with multiple-ion doping

MnZn soft magnetic ferrites have been widely utilized in power electronics, owing to the combined merits of high permeability and low energy loss. However, their deployment would result in a drastic increase in power dissipation at >3 MHz, thus limiting the scope extent of miniaturization, together with their efficiency. Here, we report a high-performance MnZn ferrite by doping multiple ions (La, Ti, Si, Ca) at grain boundaries, achieving the most optimized power loss of 267 kW/m(3) at 5 MHz (10 m T, 100 degrees C) and initial permeability of 644, which is much better than the previously reported results and commercial products. Such an improvement is attributed to weakened magnetic exchange coupling at grain-boundary regions, associated with a significant transition from the multi- to mono-domain structures, originating physically from large crystallographic mis-orientations (>25 degrees). The present study bears important significance in understanding the intrinsic correlation between the crystallographic mis-orientation and magnetic domain structure, and provides an alternative way for optimizing high-frequency soft magnetic ferrites. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.