Two-dimensional vibrational correlation spectroscopic study on the crystallization process of poly(ethylene-2,6-naphthalate)

被引：10
|
作者：
Kimura, F
Komatsu, M
Kimura, T
机构：
[1] Tokyo Metropolitan Univ, Fac Engn, Dept Appl Chem, Tokyo 1920397, Japan
[2] Nicolet Japan Corp, Kanagawa Ku, Yokohama, Kanagawa 2210022, Japan
来源：
APPLIED SPECTROSCOPY | 2000年 / 54卷 / 07期
关键词：
FT-IR spectroscopy; poly(ethylene-2,6-naphthalate); crystallization process; two-dimensional vibrational correlation; spectroscopy;
D O I：
10.1366/0003702001950706
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
Conformation changes during the crystallization process of poly(ethylene-2,6-naphthalate), including the induction period, were investigated by means of generalized two-dimensional correlation spectroscopy. A broad carbonyl stretching vibration band, as well as a broad band for a naphthalene ring vibration, was resolved in terms of the coplanarity of the carbonyl and the naphthalene ring. A difference in conformation change was found between cold crystallization and melt crystallization.
引用
收藏
页码：974 / 977
页数：4
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