Water-induced stabilization of ZnS nanoparticles

被引:38
|
作者
Goswami, N [1 ]
Sen, P [1 ]
机构
[1] Jawaharlal Nehru Univ, Sch Phys Sci, New Delhi 110067, India
关键词
nanostructures; semiconductors; nanofabrications; X-ray scattering;
D O I
10.1016/j.ssc.2004.09.022
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Surface states become important in particles with reduced size as the surface to volume ratio increases. Here we provide direct evidence of water-induced structure buildup and stabilization of nanocrystalline ZnS. The ZnS nanoparticles, prepared employing a non-equilibrium route, provide an ideal platform to investigate microscopic details of water induced structural transformation and thus demonstrate the role of S-H interactions in the time-evolution of crystalline behaviour in these particles. The colossal changes observed make these materials ideal for water sensing. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:791 / 794
页数:4
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