{2,2′-[(R,R)-Cyclohexane-1,2-diylbis(nitrilomethylidyne)]bis[6-tert-butyl-4-(triphenylphosphoniomethyl)phenolato]-O,N,N′O′}copper(II) dichloride hexakis(deuterochloroform) solvate

被引:3
|
作者
Pajunen, A
Mutikainen, I
Haikarainen, A
Sipilä, J
Pietikäinen, P
机构
[1] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland
[2] Univ Helsinki, Dept Chem, Organ Chem Lab, FIN-00014 Helsinki, Finland
关键词
D O I
10.1107/S0108270100009203
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, [Cu(C66H68N2O2P2)]Cl-2. 6CDCl(3), consists of complex cations, chloride ions and deuterochloroform solvate molecules. The complex cation crystallizes in two different conformations. In both cases, Cu II ions lie on twofold axes and the geometry around them is slightly distorted square planar. The dihedral angles between the N/Cu/N and O/Cu/O planes are 5.6 (9) and 3.9 (10)degrees for molecules A and B, respectively.
引用
收藏
页码:E321 / E322
页数:2
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