Transition Metal Catalyzed Enantioselective Migratory Functionalization Reactions of Alkenes through Chain-Walking

被引：27
|
作者：
Zhang, Min [1 ]
Ji, Yuqi [1 ]
Zhang, Chun [1 ,2 ]
机构：
[1] Tianjin Univ, Inst Mol Plus, Dept Chem, Tianjin Key Lab Mol Optoelect Sci,Sch Sci, Weijin Rd 92, Tianjin 300072, Peoples R China
[2] Haihe Lab Sustainable Chem Transformat, Tianjin 300192, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2022年 / 40卷 / 13期
基金：
中国国家自然科学基金;
关键词：
Chain-walking; Transition-metal catalysis; Enantioselectivity; Regioselectivity; Diastereoselectivity; HECK-MATSUDA DESYMMETRIZATION; STEREOSELECTIVE-SYNTHESIS; NUCLEOPHILIC ALLYLATION; ACYCLIC OLEFINS; ARYLATIONS; ALKENYLATION; DIFUNCTIONALIZATION; 1,1-DIARYLATION; POLYMERIZATION; ISOMERIZATION;
D O I：
10.1002/cjoc.202200072
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Comprehensive Summary "Chain-walking" reactions could realize to modify a molecule at the position far away from the active site. It has been a hot topic in the research field of organic synthesis. As a number of achievements have been made by researchers, the products of transition metal-catalyzed chain-walking reactions could be obtained with good enantioselectivity. This review summarized the researches on the asymmetric chain-walking reactions catalyzed by transition metal in the past decade. These works are classified according to the species of metal catalysts.
引用
收藏
页码：1608 / 1622
页数：15
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