Voltammetric determination of phytochelatins using copper solid amalgam electrode

被引：52
|
作者：
Yosypchuk, B [1 ]
Sestáková, I [1 ]
Novotny, L [1 ]
机构：
[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague 8, Czech Republic
来源：
TALANTA | 2003年 / 59卷 / 06期
关键词：
phytochelatins; cathodic stripping; copper solid amalgam electrode;
D O I：
10.1016/S0039-9140(03)00023-7
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Voltammetric determination of synthetically prepared phytochelatins (gamma-Glu-Cys)(2)Gly (PC2) and (gamma-Glu-Cys)(3)Gly (PC3) has been studied using new type of copper solid amalgam electrode. The determination, based on the formation of cuprous complexes in buffer pH 8.1, is suitable for concentrations of PC in the range 10-100 nmol l(-1). Reproducibility, employing electrochemical cleaning of the electrode surface, was statistically evaluated. The achieved limit of detection (2.1-2.6 x 10(-9) mol l(-1) for DCV measurement) together with the robust character of the electrode offer its use for detection of PCs in separated extracts of real samples. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：1253 / 1258
页数：6
相关论文
共 50 条
  • [1] Voltammetric determination of leucovorin using silver solid amalgam electrode
    Selesovska, R.
    Bandzuchova, L.
    Navratil, T.
    Chylkova, J.
    ELECTROCHIMICA ACTA, 2012, 60 : 375 - 383
  • [2] Voltammetric Determination of Insecticide Imidacloprid Using Silver Solid Amalgam Electrode
    Stepankova, Michaela
    Selesovska, Renata
    Janikova-Bandzuchova, Lenka
    Chylkova, Jaromira
    CHEMICKE LISTY, 2015, 109 (07): : 527 - 534
  • [3] Voltammetric Determination of Dinitronaphthalenes Using a Silver Solid Amalgam Paste Electrode
    Jana Tvrdikova
    Ales Danhel
    Vlastimil Vyskocil
    Jiri Barek
    Analytical Sciences, 2012, 28 : 411 - 415
  • [4] Voltammetric Determination of Dinitronaphthalenes Using a Silver Solid Amalgam Paste Electrode
    Tvrdikova, Jana
    Danhel, Ales
    Vyskocil, Vlastimil
    Barek, Jiri
    ANALYTICAL SCIENCES, 2012, 28 (04) : 411 - 415
  • [5] Voltammetric determination of ketoconazole using a polished silver solid amalgam electrode
    de Sousa Dantas, Allan Nilson
    De Souza, Djenaine
    Soares de Lima, Janete Eliza
    de Lima-Neto, Pedro
    Nunes Correia, Adriana
    ELECTROCHIMICA ACTA, 2010, 55 (28) : 9083 - 9089
  • [6] Voltammetric Determination of Nitronaphthalenes at a Silver Solid Amalgam Electrode
    Peckova, Karolina
    Barek, Jiri
    Navratil, Tomas
    Yosypchuk, Bogdan
    Zima, Jiri
    ANALYTICAL LETTERS, 2009, 42 (15) : 2339 - 2363
  • [7] Voltammetric determination of nitrophenols at a silver solid amalgam electrode
    Fischer, Jan
    Vanourkova, Lenka
    Danhel, Ales
    Vyskocil, Vlastimil
    Cizek, Karel
    Barek, Jiri
    Peckova, Karolina
    Yosypchuk, Bogdan
    Navratil, Tomas
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2007, 2 (03): : 226 - 234
  • [8] Voltammetric determination of sulfur in biodiesel microemulsion using a silver solid amalgam electrode
    Modenes Junior, Marco Antonio
    Beluomini, Maisa Azevedo
    Stradiotto, Nelson Ramos
    ANALYTICAL METHODS, 2022, 14 (36) : 3512 - 3520
  • [9] Voltammetric Determination of Insecticide Thiamethoxam on Silver Solid Amalgam Electrode
    Chorti, Parthena
    Fischer, Jan
    Vyskocil, Vlastimil
    Economou, Anastasios
    Barek, Jiri
    ELECTROCHIMICA ACTA, 2014, 140 : 5 - 10
  • [10] VOLTAMMETRIC DETERMINATION OF DINITROPHENOLS AT A SILVER SOLID AMALGAM PASTE ELECTRODE
    Tvrdikova, Jana
    Danhel, Ales
    Barek, Jiri
    CHEMICKE LISTY, 2010, 104 : S57 - S60
12345