Syntheses, reactions and crystal structures of 1,3-alternate p-tert-butylthiacalix[4]arene esters and amides

被引：12
|
作者：
Liu, Li [1 ]
Huang, Kun [1 ]
Yan, Chao Guo [1 ]
机构：
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2010年 / 66卷 / 3-4期
基金：
中国国家自然科学基金;
关键词：
Calixarene; Thiacalixarene; Alkylation; Conformation; Crystal structure; LOWER-RIM; DERIVATIVES; BEHAVIOR;
D O I：
10.1007/s10847-009-9652-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
p-tert-Butylthiacalix[4]arene was efficiently alkylated in the system of K2CO3/KI/acetone to give several thiacalixarene derivatives in 1,3-alternate conformation with functional ester, chloro, cyano and amide groups. Thiacalixarene tetraacateate can be converted to bicyclic amides by ammonolysis with alkylenediamine, and to sulfonylcalixarene by oxidation with hydrogen peroxide in acetic acid. Single crystal X-ray diffraction analysis reveals that thiacalixarene and sulfonylcalixarene exist mainly in 1,3-alternate conformation.
引用
收藏
页码：349 / 355
页数：7
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