PREPARATION AND PHOTOCHEMICAL PROPERTIES OF [2]ROTAXANES CONTAINING AN ANILINE MOIETY ENCAPSULATED BY CROWN ETHERS

被引：7

作者：

Tokunaga, Yuji ^{[1
]}

Nakashima, Satoshi ^{[1
]}

Iwamoto, Takuya ^{[1
]}

Gambayashi, Kei ^{[3
]}

Hisada, Kenji ^{[3
]}

Hoshi, Tomonori ^{[2
]}

机构：

[1] Univ Fukui, Fac Engn, Dept Mat Sci & Engn, Bunkyo Ku, Fukui 9108507, Japan

[2] Tohoku Univ, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan

[3] Univ Fukui, Fac Engn, Dept Fiber Amen Engn, Fukui 9108507, Japan

来源：

HETEROCYCLES | 2010年 / 80卷 / 02期

关键词：

Rotaxane; Aniline; Crown Ether; UV-VIS and Emission Spectra; THERMODYNAMIC CONTROL; DERIVATIVES; COMPLEXES; ROTAXANE;

D O I：

10.3987/COM-09-S(S)92

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes preparation of rotaxanes having an aniline moiety in the axle and crown ethers as wheels through an imine formation reaction and hydrogen-bond-guided self-assembly. UV-vis and emission measurements of the rotaxanes show that both absorption and fluorescence bands shift to longer wavelengths as compared to those of the unencapsulated axle component.

引用

页码：819 / 823

页数：5

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