Synthesis and crystal structure of the chiral-linked tetrahedral cluster [(μ3-Se)RuCo2(CO)8]2 (DIOP)

被引:0
|
作者
Zhu, BH
Hong, H
Yin, YQ [1 ]
Sun, J
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
[3] Inner Mongolia Univ, Chem & Chem Engn Coll, Hohhot 010021, Peoples R China
关键词
chiral; Ru-Co cluster; tetrahedral; DIOP; X-ray;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new chiral Ru-Co mixed-metal linked tetrahedral cluster [(mu(3)-Se)RUCO2(CO)(8)](2)(DIOP) 3 has been synthesised from reaction between ( mu(3)-Se)RuCo2(CO)(9) 1 and the (-)-DIOP [ 2 (2,2-dimethyl-1,3-dioxolane-4,5-diylbis-methylene) bisdiphenylphosphine] diphosphine compound. The structure of cluster 3 has been established by single-crystal X-ray diffraction method.
引用
收藏
页码:756 / 757
页数:2
相关论文
共 50 条
  • [1] Synthesis and characterization of new RuCoM (M = Co, Mo) mixed-metal linked tetrahedral clusters containing (-)-DIOP and reaction of [(μ3-Se)RuCo2(CO)8]2((-)-DIOP) with Na[Mo(CO)3(η5-C5H4COCH3)]
    Zhu, BH
    Hu, B
    Yin, YQ
    Sun, J
    POLYHEDRON, 2005, 24 (15) : 2055 - 2061
  • [2] Reaction of (μ3-Se)RuCo2(CO)9:: Synthesis and crystal structure of the chiral skeleton clusters (μ3-Se)RuCoM(CO)8[C5H3(CH3)(COCH3)] (M = Mo, W)
    Ding, ER
    Wu, SL
    Li, QS
    Yin, YQ
    Sun, J
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1999, 29 (04): : 565 - 575
  • [3] Linked cluster complex:: Crystal structure of [RuCo2 (CO)9](μ3-η2HC2CH2OC6H4OCH2C2Hη2-μ3)[RuCo2(CO)9]
    Chen, XN
    Zhang, J
    Yin, LQ
    Wang, WL
    CHEMISTRY LETTERS, 1999, (07) : 583 - 584
  • [4] Synthesis, structure, and some reactions of the cluster complex [(μ-H)2Fe5(μ3-Se)2(CO)14]
    Bashirov, D. A.
    Pushkarevsky, N. A.
    Vitovets, A. V.
    Fuhr, O.
    Konchenko, S. N.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (10) : 739 - 749
  • [5] Reactions of dipropargyl oxalate with Co2(CO)8, RuCo2(CO)11 and crystal structure of (COOCH2C2H-μ)2[Co2(CO)6]2
    Zhang, YH
    Chen, XN
    Zhang, J
    Yin, YQ
    Wu, JJ
    Huang, ZX
    JOURNAL OF CHEMICAL RESEARCH-S, 2000, (08): : 378 - 379
  • [6] Synthesis of single and double μ3-Se-containing tetrahedral MCoFe(μ3-Se) and MNiFe(μ3-Se) (M = Mo, W) clusters via isolobal and functional reactions.: Crystal and molecular structure of η5-MeO2CC5H4(CO)2WCoFe(μ3-Se)(CO)6
    Song, LC
    Dong, YB
    Hu, QM
    Huang, XY
    JOURNAL OF COORDINATION CHEMISTRY, 1999, 47 (02) : 369 - 380
  • [7] Synthesis, structure, and some reactions of the cluster complex [(μ-H)2Fe5(μ3-Se)2(CO)14]
    D. A. Bashirov
    N. A. Pushkarevsky
    A. V. Vitovets
    O. Fuhr
    S. N. Konchenko
    Russian Journal of Coordination Chemistry, 2008, 34 : 739 - 749
  • [8] Synthesis and crystal structure of [Fe3(μ3-Se)(μ3-CO)(CO)9]
    Virovets, AV
    Konchenko, SN
    Fenske, D
    JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 43 (04) : 694 - 696
  • [9] Study on the reactivity of RuCo2(μ3-S)(CO)9:: synthesis and characterization of the cluster complexes containing the tetrahedral core MRuCoS (M = Mo, W) and the two tetrahedral core MRuCoS clusters
    Ding, ER
    Wu, SL
    Xia, CG
    Yin, YQ
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 568 (1-2) : 157 - 163
  • [10] Synthesis and structure of the cluster Fe2Mo2(μ3-Se) (μ3-AsMe)(μ3-CO)(μ-CO)(CO)5(η5-Cp)2
    Konchenko, SN
    Virovets, AV
    Petrov, PA
    Tkachev, SV
    RUSSIAN CHEMICAL BULLETIN, 1999, 48 (05) : 988 - 990