Mossbauer effect of impurity pentavalent iron ions in K3MnO4

被引：0
|
作者：
Perfil'ev, YD [1 ]
Kulikov, LA [1 ]
Yurchenko, AY [1 ]
机构：
[1] Moscow State Univ, Moscow 119899, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2000年 / 45卷 / 10期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Mossbauer spectra of pentavalent iron ions in the tetrahedral position of K3MnO4 were measured at 80-295 K for the first time. The room-temperature Mossbauer parameters are the following: the isomer shift from sodium nitroprusside is delta = -0.292(1) mm/s, and the quadrupole splitting is DeltaE = 0.158(5) mm/s. The compound undergoes a phase transition at 200 K.
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页码：1568 / 1570
页数：3
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