Electrogenerated chemiluminescence of poly[(2,2'-bipyridyl) (4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridyl)2]ruthenium (II) film

被引：10
|
作者：
Ding, Shou-Nian [1 ]
Cosnier, Serge [2 ]
Shan, Dan [3 ]
Sun, Yue-Ming [1 ]
Wang, Yao [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
[2] Univ Grenoble 1, CNRS, ICMG FR 2607, Dept Chim Mol,UMR 5250, F-38041 Grenoble, France
[3] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Peoples R China
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Electrogenerated chemiluminescence (ECL); Electropolymer; Poly[(2,2'-bipyridyl)(4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridyl)(2)]ruthenium (II); Redox-cycling; Oxidative-reduction; POLYPYRROLE; ELECTROPOLYMERIZATION; PHTHALOCYANINE; DERIVATIVES; COMPLEXES; POLYMER; BASE;
D O I：
10.1016/j.elecom.2010.04.017
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Elelctrogenerated chemiluminescence (ECL) of electropolymerized films based on [(2,2'-bipyridyl)(4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-biPyridyl)(2)]ruthenium (II) was firstly investigated in both organic and aqueous solution. The ECL behaviors have been explained by two typical mechanisms, namely, redox-cycling type and oxidative-reduction type. For the former, no co-reactant was required and for the latter, tripropylamine (TPA) and (NH4)(2)C2O4 were selected as co-reactants in the organic and aqueous system, respectively. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：905 / 908
页数：4
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