Synthesis of ordered mesoporous Mg-Al composite oxide-supported potassium catalysts for biodiesel production

被引：6

作者：

Pan, Dahai ^{[1
]}

Liu, Tonglian ^{[1
]}

Yu, Feng ^{[1
]}

Chen, Shuwei ^{[1
]}

Yan, Xiaoliang ^{[1
]}

Shi, Xiufeng ^{[1
]}

Fan, Binbin ^{[1
]}

Li, Ruifeng ^{[1
]}

机构：

[1] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Shanxi, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2018年 / 116卷

基金：

中国国家自然科学基金; 山西省青年科学基金;

关键词：

Solid basic catalysts; Porous materials; Nanocomposites; Transesterification; Biodiesel; HETEROGENEOUS CATALYSTS; FACILE SYNTHESIS; ALUMINA; TRANSESTERIFICATION;

D O I：

10.1016/j.catcom.2018.08.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ordered mesoporous Mg-Al composite oxide-supported K catalysts (xK/OMMA) were prepared and used for soybean oil transesterification with methanol. The prepared xK/OMMA demonstrated a much higher soybean oil conversion (up to 97.0%) along with a 99.8% selectivity to fatty acid methyl ester and a desirable reusability, compared with K-based catalysts prepared with the same K loading and using ordered mesoporous alumina or mesoporous Mg-Al mixed oxide as support. The superior catalytic performance of xK/OMMA is associated with the excellent structural and surface properties of support OMMA, thus benefiting the generation of catalytically active sites and their highly homogenous dispersion.

引用

页码：76 / 80

页数：5

共 50 条

[1] Rational design of Mg-Al mixed oxide-supported bimetallic catalysts for dry reforming of methane
Tsyganok, AI
Inaba, M
Tsunoda, T
Uchida, K
Suzuki, K
Takehira, K
Hayakawa, T
APPLIED CATALYSIS A-GENERAL, 2005, 292 : 328 - 343
[2] Preparation of Pt supported on mesoporous Mg-Al oxide catalysts for efficient dehydrogenation of methylcyclohexane
Wu, Kui
Chen, Fengtao
Wang, Feng
Huang, Yanping
Shen, Zhigang
Wang, Weiyan
Yang, Yunquan
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (50) : 25513 - 25519
[3] Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported ordered mesoporous silica catalysts
Chae, Ho-Jeong
Kim, Tae-Wan
Moon, Young-Kyun
Kim, Han-Kyu
Jeong, Kwang-Eun
Kim, Chul-Ung
Jeong, Soon-Yong
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 : 596 - 604
[4] Structured catalysts based on Mg-Al hydrotalcite for the synthesis of biodiesel
Reyero, I.
Velasco, I.
Sanz, O.
Montes, M.
Arzamendi, G.
Gandia, L. M.
CATALYSIS TODAY, 2013, 216 : 211 - 219
[5] BIODIESEL PRODUCTION FROM CANOLA OIL OVER ZINC OXIDE-SUPPORTED CATALYSTS
Boz, Nezahat
Sunal, Oylum
JOURNAL OF THE FACULTY OF ENGINEERING AND ARCHITECTURE OF GAZI UNIVERSITY, 2009, 24 (03): : 389 - 395
[6] Mesoporous calcined Mg-Al hydrotalcites as catalysts for synthesis of propylene glycol
W, Gongde
Wang, Xiaoli
Li, Junping
Zhao, Ning
Wei, Wei
Sun, Yuhan
RECENT PROGRESS IN MESOSTRUCTURED MATERIALS, PROCEEDINGS OF THE 5TH INTERNATIONAL MESOSTRUCTURED MATERIALS SYMPOSIUM - IMMS2006, 2007, 165 : 773 - 776
[7] Physico-chemical and catalytic properties of Mg-Al hydrotalcite and Mg-Al mixed oxide supported copper catalysts
Dixit, Manish
Mishra, Manish
Joshi, P. A.
Shah, D. O.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (02) : 458 - 468
[8] Synthesis of ordered macro-mesoporous Mg-Al composite oxides with high thermal stability and mechanical strength
Pan, Dahai
Chen, Wei
Yu, Feng
Chen, Shuwei
Yan, Xiaoliang
Shi, Xiufeng
Fan, Binbin
Li, Ruifeng
MATERIALS LETTERS, 2018, 224 : 33 - 36
[9] Investigation of biodiesel production from canola oil using Mg-Al hydrotalcite catalysts
Ilgen, Oguzhan
Dincer, Ismail
Yildiz, Meltem
Alptekin, Ertan
Boz, Nezahat
Canakci, Mustafa
Akin, Ayse Nilgun
TURKISH JOURNAL OF CHEMISTRY, 2007, 31 (05) : 509 - 514
[10] Outstanding performance of rehydrated Mg-Al hydrotalcites as heterogeneous methanolysis catalysts for the synthesis of biodiesel
Navajas, A.
Campo, I.
Moral, A.
Echave, J.
Sanz, O.
Montes, M.
Odriozola, J. A.
Arzamendi, G.
Gandia, L. M.
FUEL, 2018, 211 : 173 - 181

← 1 2 3 4 5 →