Crown ether-type organic composite adsorbents embedded in high-porous silica beads for simultaneous recovery of lithium and uranium in seawater

被引：16

作者：

Tachibana, Yu ^{[1
]}

Tanaka, Masahiro ^{[2
]}

Nogami, Masanobu ^{[3
]}

机构：

[1] Nagaoka Univ Technol, Dept Nucl Syst Safety Engn, Grad Sch Engn, 1603-1 Kamitomioka Machi, Nagaoka, Niigata 9402188, Japan

[2] Natl Inst Fus Sci, 322-6 Oroshi Cho, Toki, Gifu 5095292, Japan

[3] Kindai Univ, Dept Elect & Elect Engn, 3-4-1 Kowakae, Higashiosaka, Osaka 5778502, Japan

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2019年 / 322卷 / 02期

基金：

日本学术振兴会;

关键词：

Crown ether-type organic composite adsorbent; High-porous silica beads; Lithium; Uranium; Seawater; Simultaneous recovery; LIQUID-PHASE ADSORPTION; THERMODYNAMIC PARAMETERS; SIMULTANEOUS REMOVAL; EXTRACTION; AMIDOXIME; POLYMER; RESIN; SIZE;

D O I：

10.1007/s10967-019-06792-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The syntheses of crown ether-type organic composite adsorbents embedded in high-porous silica beads for simultaneous recovery of lithium and uranium in seawater have been achieved and the adsorption behavior of lithium and uranium on the composite adsorbents has been examined in several types of original seawater in the wide temperature and pH ranges. As a result, the composite adsorbents composed of benzo-15-crown-5 (BC15) and benzo-18-crown-6 (BC18) showed the top-class maximum adsorption capacities for lithium [6.5 mg/g (BC15), 11 mg/g (BC18)] and uranium [12 mg/g (BC15), 4.2 mg/g (BC18)].

引用

页码：717 / 730

页数：14

共 2 条

[1] Crown ether-type organic composite adsorbents embedded in high-porous silica beads for simultaneous recovery of lithium and uranium in seawater
Yu Tachibana
Masahiro Tanaka
Masanobu Nogami
Journal of Radioanalytical and Nuclear Chemistry, 2019, 322 : 717 - 730
[2] Chromatographic Purification of Lithium, Vanadium, and Uranium from Seawater Using Organic Composite Adsorbents Composed of Benzo-18-Crown-6 and Benzo-15-Crown-5 Embedded in Highly Porous Silica Beads
Tachibana, Yu
Kalak, Tomasz
Tanaka, Masahiro
ACS OMEGA, 2022, : 27410 - 27421

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