Building up 1-D, 2-D, and 3-D Polyiodide Frameworks by Finely Tuning the Size of Aryls on Ar-S-TTF in the Charge-Transfer (CT) Complexes of Ar-S-TTFs and Iodine

被引：9

作者：

Ma, Longfei ^{[1
]}

Peng, Haili ^{[1
]}

Lu, Xiaofeng ^{[1
]}

Liu, Lei ^{[1
]}

Shao, Xiangfeng ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2018年 / 36卷 / 09期

基金：

中国国家自然科学基金;

关键词：

polyiodide; tetrathiafulvalene; charge-transfer complex; crystal engineering; halogen bond; CRYSTAL-STRUCTURE; HYDROGEN-BONDS; HALOGEN BONDS; CO-CRYSTALS; STATE; RECOGNITION; RELEASE; CHAINS; SALTS;

D O I：

10.1002/cjoc.201800215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The arylthio-substituted tetrathiafulvalenes (Ar-S-TTFs) are electron donors having three reversible states, neutral, cation radical, and dication. The charge-transfer (CT) between Ar-S-TTFs (TTF1TTF3) and iodine (I-2) is reported herein. TTF1TTF3 show the CT with I-2 in the CH2Cl2 solution, but they are not completely converted into cation radical state. In CT complexes of TTF1TTF3 with I-2, the charged states of Ar-S-TTFs are distinct from those in solution. TTF1 is at cation radical state, and TTF2TTF3 are oxidized to dication. The iodine components in complexes show various structures including 1-D chain of V-shaped (I-5)(-), and 2-D and 3-D iodine networks composed of I-2 and (I-3)(-).

引用

页码：845 / 850

页数：6