Cyclohepta[c]furan-based fluorophores: Synthesis, optical properties, solvatochromism and DFT study

被引：1

作者：

Yanagisawa, Tatsuya ^{[1
]}

Kobayashi, Naoki ^{[2
]}

Miyatake, Ryuta ^{[3
]}

Oda, Mitsunori ^{[2
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[2] Shinshu Univ, Grad Sch Sci & Technol, Asahi 3-1-1, Matsumoto, Nagano 3908621, Japan

[3] Univ Toyama, Grad Sch Sci & Engn Educ, Gofuku 3190, Toyama 9308555, Japan

来源：

DYES AND PIGMENTS | 2017年 / 143卷

关键词：

6H-cyclohepta[c]furan; Fluorescence; Solvatochromism; TD-DFT calculations; FLUORESCENCE; DERIVATIVES; SOLVENT;

D O I：

10.1016/j.dyepig.2017.04.035

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Novel 6H-cyclohepta[c]furan derivatives possessing aryl groups on 1,3-position were synthesized, and their photophysical behavior were investigated. 1,3-Diphenyl-5,7-difomyl derivative showed solvatochromism. As the electron donating ability at 1,3 -positions and the electron withdrawing ability at 5,7 -positions increased, the absorption and emission wavelengths were bathochromically shifted. Theoretical calculations revealed that their photophysical behaviors are reproduced. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：183 / 189

页数：7

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