Routes to fluorinated organic derivatives by nickel mediated C-F activation of heteroaromatics

被引：205
|
作者：
Braun, T
Perutz, RN
机构：
[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany
[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 23期
关键词：
D O I：
10.1039/b206154f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New fluorinated azaheterocycles can be synthesised regio- and chemo-selectively via C-F activation of fluorinated precursors at nickel, with subsequent functionalisation and release from the coordination sphere of the metal; the requirements for productive C- F activation are significantly different from those for C-H bond activation.
引用
收藏
页码：2749 / 2757
页数：9
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