Organic-inorganic hybrids obtained by in situ polymerization of aniline in silica/phosphonate matrix

被引：8
|
作者：
Plesu, Nicoleta [1 ]
Ilia, Gheorghe [1 ,3 ]
Sfirloaga, Paula [2 ]
Iliescu, Smaranda [1 ]
机构：
[1] Romanian Acad, Inst Chem, 24 Mihai Viteazul Bvd, Timisoara 300223, Romania
[2] Natl Res Inst Electrochem & Condensed Matter, Timisoara 300224, Romania
[3] West Univ, Fac Chem Biol & Geog, Timisoara 300115, Romania
来源：
JOURNAL OF MATERIALS SCIENCE | 2009年 / 44卷 / 23期
关键词：
PHOSPHORIC-ACID; FORMIC-ACID; POLYANILINE; GELS; SURFACES;
D O I：
10.1007/s10853-009-3895-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A method for preparing organic-inorganic hybrids containing organophosphorus compounds, silica, and polyaniline (PANI) was developed using sol-gel technique. This method allows the in situ synthesis of organic-inorganic hybrids by reacting tetraethoxysilane (TEOS), aniline, initiator, organophosphorus compound in formic acid. The formic acid has multiple functions: as solvent and acidic media for polymerization of aniline and reagent for sol-gel process. The use of an organophosphorus compound as coupling agent and the introduction of a conductive polymer in silica matrix was investigated.
引用
收藏
页码：6437 / 6446
页数：10
相关论文
共 50 条
  • [1] Organic–inorganic hybrids obtained by in situ polymerization of aniline in silica/phosphonate matrix
    Nicoleta Plesu
    Gheorghe Ilia
    Paula Sfirloaga
    Smaranda Iliescu
    Journal of Materials Science, 2009, 44 : 6437 - 6446
  • [2] Organic-inorganic hybrids containing phosphonate groups obtained by sol-gel process
    Ilia, G.
    Parvulescu, V.
    Popa, A.
    Iliescu, S.
    JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 2008, 10 (12): : 3398 - 3402
  • [3] Drug Delivery Systems Obtained from Silica Based Organic-Inorganic Hybrids
    Oshiro Junior, Joao Augusto
    Abucafy, Marina Paiva
    Manaia, Eloisa Berbel
    da Silva, Bruna Lallo
    Chiari-Andreo, Bruna Galdorfini
    Chiavacci, Leila Aparecida
    POLYMERS, 2016, 8 (04)
  • [4] PREPARATION OF POLYIMIDE - SILICA ORGANIC-INORGANIC HYBRIDS
    OBER, CK
    JOHNEN, NA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 287 - POLY
  • [5] Synthesis of silica gels and organic-inorganic hybrids on their base
    Khimich, NN
    GLASS PHYSICS AND CHEMISTRY, 2004, 30 (05) : 430 - 442
  • [6] Synthesis of Silica Gels and Organic-Inorganic Hybrids on Their Base
    N. N. Khimich
    Glass Physics and Chemistry, 2004, 30 : 430 - 442
  • [7] Bacterial cellulose-silica organic-inorganic hybrids
    Barud, H. S.
    Assuncao, R. M. N.
    Martines, M. A. U.
    Dexpert-Ghys, J.
    Marques, R. F. C.
    Messaddeq, Y.
    Ribeiro, S. J. L.
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2008, 46 (03) : 363 - 367
  • [8] New polyimide-silica organic-inorganic hybrids
    Huang, Y
    Gu, Y
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (09) : 2210 - 2214
  • [9] Organic-inorganic polymer hybrids utilizing in-situ ring-opening cationic polymerization
    Iwamura, T. (iwamura@chujo.synchem.kyoto-u.ac.jp), 1600, (Society of Polymer Science):
  • [10] Organic-inorganic polymer hybrids and porous materials obtained on their basis
    Cazacu, M
    Dragan, S
    Vlad, A
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (08) : 2060 - 2067
12345