Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) π-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand

被引：91
|
作者：
Brown, Timothy J. [1 ]
Dickens, Marina G. [1 ]
Widenhoefer, Ross A. [1 ]
机构：
[1] Duke Univ, French Family Sci Ctr, Durham, NC 27708 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 42期
基金：
美国国家科学基金会;
关键词：
GOLD(I)-CATALYZED INTRAMOLECULAR HYDROAMINATION; ACETYLENE COMPLEXES; CATALYSIS; ETHYLENE; ALLENES; ALKYNES; AU; BOND; CYCLOADDITIONS; REACTIVITY;
D O I：
10.1039/b914632f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A number of cationic gold pi-alkene complexes of the form {[P(t-Bu)(2)o-biphenyl]Au(pi-alkene)} +SbF6- were isolated and three were analyzed by X-ray crystallography.
引用
收藏
页码：6451 / 6453
页数：3
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