The free radical chemistry of tert-butyl formate:: rate constants for hydroxyl radical, hydrated electron and hydrogen atom reaction in aqueous solution

被引：28

作者：

Hardison, DR

Cooper, WJ

Mezyk, SP ^{[1
]}

Bartels, DM

机构：

[1] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

[2] Univ N Carolina, Dept Chem, Wilmington, NC 28403 USA

[3] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

来源：

RADIATION PHYSICS AND CHEMISTRY | 2002年 / 65卷 / 4-5期

关键词：

tert-butyl formate (TBF); methyl tert-butylether (MTBE); advanced oxidation technology (AOT); rate constraints; free radicals; aqueous electron pulse radiolysis;

D O I：

10.1016/S0969-806X(02)00333-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transients generated in situ by advanced oxidation technologies (AOTs) to destroy organic contaminants in ground and drinking water often give large concentrations of chemical by-products. These by-products may have adverse health effects, and can also interfere with the desired chemical removal by competing for the generated transients, thus lowering the overall efficiency of the remediation process. To allow for a quantitative evaluation of the influence of tertbutyl formate (TBF), a major by-product formed in the AOT destruction of methyl tert-butyl ether, rate constants for TBF reaction with the hydroxyl radical, the hydrated electron and the hydrogen atom in aqueous solution were measured in this study. Absolute values of (5.23+/-0.07) x 10(8), (5.48+/-0.09) x 10(8) and (3.58+/-0.07) x 10(6) M(-1)s(-1), were determined at 22degreesC, respectively. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：309 / 315

页数：7

共 50 条

[1] RATE CONSTANTS OF THE REACTION OF THE HYDRATED ELECTRON AND HYDROXYL RADICAL WITH OZONE IN AQUEOUS-SOLUTION
BAHNEMANN, D
HART, EJ
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (02): : 252 - 255
[2] Absolute rate constants for the reaction of the hydrated electron, hydroxyl radical and hydrogen atom with chloroacetones in water
Williams, JA
Cooper, WJ
Mezyk, SP
Bartels, DM
[J]. RADIATION PHYSICS AND CHEMISTRY, 2002, 65 (4-5) : 327 - 334
[3] RATE CONSTANTS FOR HYDROGEN ATOM AND HYDROXYL RADICAL REACTIONS IN AQUEOUS SOLUTION
THOMAS, JK
[J]. RADIATION RESEARCH, 1963, 19 (01) : 181 - &
[4] Rate constants of reactions of κ-carrageenan with hydrated electron and hydroxyl radical
Abad, L. V.
Saiki, S.
Kudo, H.
Muroya, Y.
Katsumura, Y.
de la Rosa, A. M.
[J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2007, 265 (01): : 410 - 413
[5] Arrhenius parameter determination for the reaction of the oxide radical, hydrated electron and hydroxyl radical with iodate in aqueous solution
Mezyk, SP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (12): : 2251 - 2254
[6] RATE CONSTANTS FOR THE REACTION OF TERT-BUTYL RADICALS WITH CHLOROFORM IN SOLUTION
DUTSCH, HR
FISCHER, H
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1981, 13 (06) : 527 - 541
[7] NUCLEOPHILIC CHARACTER OF THE TERT-BUTYL RADICAL - ABSOLUTE RATE CONSTANTS FOR THE REACTIONS WITH SUBSTITUTED TOLUENES
DUTSCH, HR
FISCHER, H
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (02) : 195 - 200
[8] SPECIFIC RATE CONSTANTS OF HYDROXYL RADICAL AND HYDRATED ELECTRON REACTIONS DETERMINED BY RCL METHOD
PRUTZ, WA
VOGEL, S
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1976, 31 (11): : 1501 - 1510
[9] Rate coefficients of hydroxyl radical reaction with dimethyl ether and methyl tert-butyl ether over an extended temperature range
Arif, M
Dellinger, B
Taylor, PH
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (13): : 2436 - 2441
[10] The radical versus ionic mechanisms of reduced cobalamin inactivation by tert-butyl hydroperoxide and hydrogen peroxide in aqueous solution
Salnikov, Denis S.
Makarov, Sergei V.
Koifman, Oscar I.
[J]. NEW JOURNAL OF CHEMISTRY, 2021, 45 (02) : 535 - 543

← 1 2 3 4 5 →