The solubilities and enthalpies of a solution of polyvinyltetrazoles in organic solvents

被引：0
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作者：
Kizhnyaev, VN
Gorkovenko, OP
Bazhenov, DN
Smirnov, AI
机构：
来源：
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1997年 / 39卷 / 05期
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The dissolution of polyvinyltetrazoles of various structures in organic solvents was studied by calorimetry. The solubility of these polymers is controlled by competition between their self-association and the donor-acceptor interaction with the solvent. A relationship between the heat of solution and the physicochemical parameters of the solvents was established for poly(2-methyl-5-vinyl)tetrazole. The heats of solution of poly(5-vinyltetrazole)s bearing methyl substituents depend on the procedure of preparation and are governed by the packing density of these polymers.
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页码：856 / 861
页数：6
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