Push-pull ruthenium diacetylide complexes: new dyes for p-type dye-sensitized solar cells

被引：34

作者：

Lyu, Siliu ^{[1
]}

Farre, Yoann ^{[2
]}

Ducasse, Laurent ^{[1
]}

Pellegrin, Yann ^{[2
]}

Toupance, Thierry ^{[1
]}

Olivier, Celine ^{[1
]}

Odobel, Fabrice ^{[2
]}

机构：

[1] Univ Bordeaux, CNRS, UMR 5255, Inst Sci Mol, 351 Cours Liberat, F-33405 Talence, France

[2] CNRS, UMR 6230, Fac Sci & Tech Nantes, CEISAM, 2 Rue Houssiniere, Nantes 3, France

来源：

RSC ADVANCES | 2016年 / 6卷 / 24期

关键词：

NIO; PHOTOSENSITIZER; PERFORMANCE; EFFICIENCY; INJECTION; DONOR;

D O I：

10.1039/c5ra25899e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A couple of novel donor-pi-acceptor dyes based on organometallic ruthenium diacetylide complexes (SL1 and SL2) have been designed and synthesized for use in NiO-based p-type dye-sensitized solar cells (p-DSCs). The optical and electrochemical properties of the dyes were assessed and theoretical calculations were performed to rationalize the experimental data. The best performing dye in NiO-based p-DSC devices is the red dye SL1, which gives a photocurrent density of 2.25 mA cm(-2) and maximum IPCE of 18%. This represents a promising result, paving the way for future finely tuned organometallic efficient dyes for such application.

引用

页码：19928 / 19936

页数：9

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