Effect of copper concentration on the structure of intermetallics and graphite additives of Al-Cu/C powder composites

被引:3
|
作者
Matvienko, Yana, I [1 ]
Rud, Alexander D. [1 ]
Rud, Nikolai D. [1 ]
Fesenko, Olena M. [2 ]
Yaremkevich, Andriy D. [2 ]
Trachevski, Volodymir V. [3 ]
机构
[1] NAS Ukraine, GV Kurdyumov Inst Met Phys, Vernadsky Blvd 36, UA-03142 Kiev, Ukraine
[2] NAS Ukraine, Inst Phys, Ave Nauki 46, UA-03028 Kiev, Ukraine
[3] NAS Ukraine, Tech Ctr, Pokrovskaya Str 13, UA-04070 Kiev, Ukraine
关键词
Al-Cu/C powder composites; Metastable bcc-Al4Cu9 phase; A2 -> D8(3) first range ordering; Ball milling; Graphite amorphization; Al4C3; carbide; MECHANICAL-PROPERTIES; MICROSTRUCTURE; EVOLUTION; ALLOY; NI;
D O I
10.1007/s13204-021-01785-9
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The structure of hypo-eutectic and eutectic Al-Cu/C powder composites, as well as the powders with composition in the region of equilibrium Al4Cu9 phase, were studied using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and nuclear magnetic resonance (NMR) after high-energy ball milling of Al and Cu elemental powders with 5 wt.% of graphite additives and heat treatment at the temperature of 500 degrees C. Mechanical energy dose transferred into the powder composites during milling for 8 h was estimated to be 32 kJ/g and leads to the formation of the metastable disordered bcc-Al4Cu9 phase (A2 structural type) in a wide composition range. Effect of copper concentration on the peculiarities of its structure, chemical composition and the possibility of A2 -> D8(3) first range ordering after heat treatment has been examined. Graphite additives structure evolution after milling and heat treatment of copper-rich Al-Cu/C powder composites was also specified.
引用
收藏
页码:1245 / 1255
页数:11
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