A mathematical model for predicting the flash point of binary solutions

被引：127

作者：

Liaw, HJ ^{[1
]}

Lee, YH ^{[1
]}

Tang, CL ^{[1
]}

Hsu, HH ^{[1
]}

Liu, JH ^{[1
]}

机构：

[1] China Med Coll, Dept Occupat Safety & Hlth, Taichung, Taiwan

来源：

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES | 2002年 / 15卷 / 06期

关键词：

flash point; lower flammable limit; vapor-liquid equilibrium; binary solution; minimum flash point;

D O I：

10.1016/S0950-4230(02)00068-2

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A mathematical model which may be used for predicting the flash point of binary solutions has been proposed and subsequently verified by experimentally-derived data, such data pertaining to an almost-ideal solution as also to highly non-ideal solutions. The results reveal that the model is able to precisely predict the flash point over the entire composition range of binary solutions for both ideal solutions and non-ideal solutions by way of utilizing the flash point of the individual components. The highly non-ideal solution like octane+ethanol exhibits the minimum flash-point behavior, which leads to the minimum on the flash point vs composition curve. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：429 / 438

页数：10

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