Helium atom scattering from isolated CO molecules on a Pt(111) surface: Experiment versus close-coupling calculations for a realistic He-CO potential

被引：13

作者：

Choi, BH

Graham, AP

Tang, KT

Toennies, JP

机构：

[1] Max Planck Inst Stromungsforsch, D-37073 Gottingen, Germany

[2] Univ Calif Riverside, Dept Phys, Riverside, CA 92521 USA

[3] Pacific Lutheran Univ, Dept Phys, Tacoma, WA 98447 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2000年 / 112卷 / 23期

关键词：

D O I：

10.1063/1.481687

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The angular dependence of the elastic scattering of helium atoms from a low coverage (Theta(CO) = 0.03) of randomly distributed isolated CO molecules adsorbed on a Pt(111) surface has been measured over a wide range of incident helium atom beam energies between E-i=5.25 and 62.1 meV. The results are compared with a close-coupling theory for a realistic He-CO potential. From a best fit of the experimental results the distance of the molecule from the surface and a modified gas phase He-CO potential are obtained. (C) 2000 American Institute of Physics. [S0021-9606(00)01821-3].

引用

页码：10538 / 10547

页数：10

共 15 条

[1] A comparative study of the He-Sb(111) interaction potential from close-coupling calculations and helium atom scattering experiments
Kraus, Patrick
Mayrhofer-Reinhartshuber, Michael
Goesweiner, Christian
Apolloner, Florian
Miret-Artes, Salvador
Ernst, Wolfgang E.
SURFACE SCIENCE, 2014, 630 : 208 - 215
[2] Helium-surface interaction potential of Sb(111) from scattering experiments and close-coupling calculations
Mayrhofer-Reinhartshuber, M.
Kraus, P.
Tamtoegl, A.
Miret-Artes, S.
Ernst, W. E.
PHYSICAL REVIEW B, 2013, 88 (20)
[3] Surface Structure of Bi(111) from Helium Atom Scattering Measurements. Inelastic Close-Coupling Formalism
Kraus, P.
Tamtoegl, A.
Mayrhofer-Reinhartshuber, M.
Apolloner, F.
Goesweiner, Ch.
Miret-Artes, S.
Ernst, W. E.
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (30): : 17235 - 17242
[4] HELIUM ATOM DIFFERENTIAL CROSS-SECTIONS FOR SCATTERING FROM SINGLE ADSORBED CO MOLECULES ON A PT(111) SURFACE
LAHEE, AM
MANSON, JR
TOENNIES, JP
WOLL, C
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (12): : 7194 - 7203
[5] Helium atom scattering from isolated CO molecules on copper(001)
Graham, AP
Hofmann, F
Toennies, JP
Manson, JR
JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (05): : 2093 - 2098
[6] Quantum mechanical studies of helium atom scattering from isolated CO molecules on metal surfaces
Nave, S
Lemoine, D
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (24) : 6263 - 6280
[7] SELECTIVE ADSORPTION RESONANCES IN THE SCATTERING OF HELIUM-ATOMS FROM XENON COATED GRAPHITE - CLOSE-COUPLING CALCULATIONS AND POTENTIAL DEPENDENCE
HUTSON, JM
SCHWARTZ, C
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (10): : 5179 - 5187
[8] CROSS-SECTIONS FOR HE SCATTERING FROM SURFACE IMPERFECTIONS - VACANCIES AND CO ADSORBATES ON PT(111)
YINNON, AT
KOSLOFF, R
GERBER, RB
POELSEMA, B
COMSA, G
JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (06): : 3722 - 3731
[9] Interpretation of helium atom scattering from isolated CO molecules on copper (001) based on an exact quantum mechanical model
Choi, BH
Tang, KT
Toennies, JP
JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (05): : 1631 - 1633
[10] FULLY QUANTUM STUDY OF THE 3D DIFFRACTIVE SCATTERING OF HE FROM ISOLATED CO ADSORBATES ON PT(111)
CARRE, MN
LEMOINE, D
JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (06): : 5305 - 5312

← 1 2 →