Equilibrium of a Pd-based membrane reactor

被引：2
|
作者：
Barbieri, Giuseppe
Scura, Francesco
Drioli, Enrico
机构：
[1] Univ Calabria, Inst Membrane Technol, ITM, CNR, I-87030 Arcavacata Di Rende, CS, Italy
[2] Univ Calabria, Dept Chem Engn & Mat, BUCCI, I-87030 Arcavacata Di Rende, CS, Italy
来源：
DESALINATION | 2006年 / 200卷 / 1-3期
关键词：
Pd membrane reactor equilibrium; reaction conversion; hydrogen;
D O I：
10.1016/j.desal.2006.03.471
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Pd-based membrane reactors (MRs) are characterized by infinite H-2 selectivity of the membrane used: no other species permeates through an ideal Pd-based membrane. In a closed system consisting of two chambers the produced H, permeates from reaction side to permeate one, driving the reaction to a further conversion. The equilibrium state does not depend on kinetics, permeation law, membrane area or thickness, membrane nature, mixing degree etc. but depends only on temperature, retentate and permeate side pressures, molar feed ratio, sweep factor.
引用
收藏
页码：679 / 680
页数：2
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